The hydrolysis product [Ga-2(C3H7)(4)(OH)(2)].C14H32N4, derived from the tetrakis(triisopropylgallium)-1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (1/1) adduct, consists of a centrosymmetric [(Pr2Ga)-Pr-i(mu -OH)](2) unit hydrogen bonded through the hydroxyl group to a nitrogen on an adjacent centrosymmetric 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane molecule, resulting in the generation of a molecular chain through the crystal.The hydrolysis product [Ga-2(C3H7)(4)(OH)(2)].C14H32N4, derived from the tetrakis(triisopropylgallium)-1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (1/1) adduct, consists of a centrosymmetric [(Pr2Ga)-Pr-i(mu -OH)](2) unit hydrogen bonded through the hydroxyl group to a nitrogen on an adjacent centrosymmetric 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane molecule, resulting in the generation of a molecular chain through the crystal.