Peer-Reviewed Journal Details
Mandatory Fields
Flynn, CJ;Elcoate, CJ;Lawrence, SE;Maguire, AR
2010
February
Journal of the American Chemical Society
Highly Enantioselective Intramolecular Copper Catalyzed C-H Insertion Reactions of alpha-Diazosulfones
Validated
WOS: 50 ()
Optional Fields
RHODIUM CARBENOID INSERTIONS CARBON-HYDROGEN INSERTION BETA-KETO SULFONES PHENYLIODONIUM YLIDES ASYMMETRIC-SYNTHESIS BONDS CYCLOPROPANATION 2,2-DIOXIDES HETEROCYCLES SELECTIVITY
132
1184
Excellent enantiocontrol (up to 98% ee) is achieved in copper catalyzed C-H insertions of alpha-diazosulfones to form thiopyrans, with up to 60% ee in C-H insertions leading to sulfolanes.
WASHINGTON
0002-7863
10.1021/ja909713a
Grant Details