Maity, D;Drew, MGB;Godsell, JF;Roy, S;Mukhopadhyay, G

2010

March

Transition Metal Chemistry

Synthesis and characterization of Cu(II) complexes of tetradentate and tridentate symmetrical Schiff base ligands involving o-phenelenediamine, salicylaldehyde and diacetylmonoxime

Validated

WOS: 24 ()

HYDROGEN-BOND STRUCTURES COPPER(II) COMPLEXES MAGNETOSTRUCTURAL CORRELATIONS MOLECULAR-STRUCTURE MAGNETIC-PROPERTIES METAL-COMPLEXES 1ST EVIDENCE DINUCLEAR NICKEL(II) CRYSTAL

35

197

204

A mononuclear complex [CuL] (1), a binuclear complex [Cu2LCl2(H2O)] (2), a trinuclear complex [Cu3L2](ClO4)(2) (3) involving o-phenylenediamine and salicylaldehyde and another binuclear complex of a tridentate ligand (H2L1) [Cu2L (2) (1) ](CH3COO)(2) (4) involving o-phenylenediamine and diacetylmonoxime have been synthesized, where H2L = N,N'-o-phenylenebis(salicylideneimine) and H2L1 = 3-(2-aminophenylimino)butan-2-one oxime. All the complexes have been characterized by elemental analyses, spectral and magnetic studies. The binuclear complex (2) was characterized structurally where the two Cu(II) centers are connected via an oxygen-bridged arrangement.

DORDRECHT

0340-4285

10.1007/s11243-009-9314-9