Peer-Reviewed Journal Details
Mandatory Fields
Kissane, M;Lawrence, SE;Maguire, AR
2010
April
Tetrahedron: Asymmetry
Diastereoselective sulfur oxidation of 2-thio-3-chloroacrylamides
Validated
WOS: 12 ()
Optional Fields
THIO-BETA-CHLOROACRYLAMIDES ASYMMETRIC-SYNTHESIS MOLECULAR RECOGNITION AROMATIC INTERACTIONS ORGANIC SULFIDES ALPHA-THIOAMIDES SULFOXIDES TRANSFORMATION BIOTRANSFORMATION DIENOPHILES
21
871
884
Diastereoselective sulfur oxidation in 2-thio-3-chloroacrylamides is described A range of chiral amine auxiliaries was incorporated in the beta-chloroacrylamide, and the efficiency with which the stereochemistry was relayed to the sulfur centre during sulfoxidation was investigated. Diastereomeric ratios of up to 3 3 1 were achieved. (C) 2010 Elsevier Ltd. All rights reserved
OXFORD
0957-4166
10.1016/j.tetasy.2010.05.004
Grant Details