Ferguson, G;Pollock, J;McEneaney, PA;OConnell, DP;Spalding, TR;Gallagher, JF;Macias, R;Kennedy, JD

1996

March

Chemical Communications

An air-stable, cationic metallacarborane without a charge-compensated carborane ligand

Validated

WOS: 8 ()

MOLECULAR-STRUCTURES CHEMISTRY METALLAHETEROBORANES CRYSTAL

679

681

The first air-stable, cationic rhodadicarborane complex, [3-(MeCN)-3,3-(PPh(2)Me)(2)-3,1,2-closo-RhC2B9H11][SbF6] 1, which does not contain a 'charge-compensated' carborane ligand is synthesised and structurally characterised by X-ray crystallography and spectroscopic techniques (IR and NMR).

CAMBRIDGE

1359-7345