Peer-Reviewed Journal Details
Mandatory Fields
O'Keeffe, S;Harrington, F;Maguire, AR
2007
September
Synlett
Enantioselective intramolecular bfichner reaction of alpha-diazoketones
Validated
WOS: 27 ()
Optional Fields
ASYMMETRIC-SYNTHESIS
2367
2370
Enantioselectivities of up to 95% ee have been achieved in the intrarnolecular Buchner reaction catalysed by copper is oxazoline) complexes, the highest asymmetric inductions reported to date for this transformation. Significantly, use of a catalyst derived from a bis(oxazoline) ligand resulted in high enantioselectivities across several Substrates, indicating the possibility of developing a catalyst with general applicability.
STUTTGART
0936-5214
10.1055/s-2007-986626
Grant Details