Peer-Reviewed Journal Details
Mandatory Fields
Geaney, H., McNulty, D., OConnell, J., Holmes, J. D. & O'Dwyer, C.
2016
June
Journal of the Electrochemical Society
Assessing Charge Contribution from Thermally Treated Ni Foam as Current Collectors for Li-ion Batteries
Published
Optional Fields
163
A1805
A1811
In this report we have investigated the use of Ni foam substrates as anode current collectors for Li-ion batteries. As the majority of reports in the literature focus on hydrothermal formation of materials on Ni foam followed by a high temperature anneal/oxidation step, we probed the fundamental electrochemical responses of as received Ni foam substrates and those subjected to heating at 100C, 300C and 450C. Through cyclic voltammetry and galvanostatic testing, it is shown that the as received and 100C annealed Ni foam show negligible electrochemical activity. However, Ni foams heated to higher temperature showed substantial electrochemical contributions which may lead to inflated capacities and incorrect interpretations of CV responses for samples subjected to high temperature anneals. XRD, XPS and SEM analyses clearly illustrate that the formation of electrochemically active NiO nanoparticles on the surface of the foam is responsible for this behavior. To further investigate the contribution of the oxidized Ni foam to the overall electrochemical response, we formed Co3O4 nanoflowers directly on Ni foam at 450C and showed that the resulting electrochemical response was dominated by NiO after the first 10 charge/discharge cycles. This report highlights the importance of assessing current collector activity for active materials grown on transition metal foam current collectors for Li-ion applications.
http://jes.ecsdl.org/content/163/8/A1805.abstract?cpetoc
10.1149/2.0071609jes
Grant Details