Tiana, D;Hendon, CH;Walsh, A

2014

January

Chemical Communications

Ligand design for long-range magnetic order in metal-organic frameworks

Validated

Altmetric: 3 ()

SPIN-EXCHANGE INTERACTIONS PYROPHOSPHATE (VO)(2)P2O7 CHALLENGES DEVICES ROOM

50

13990

13993

We report a class of ligands that are candidates to construct metal-organic frameworks with long-range magnetic order between transition metal centres. Direct quantum chemical calculations predict Neel temperatures exceeding 100 K for the case of Mn.

CAMBRIDGE

1359-7345

10.1039/c4cc06433j