Peer-Reviewed Journal Details
Mandatory Fields
McGlacken, Gerard P. and O'Brien, Ciara T. and Whitwood, Adrian C. and Fairlamb, Ian J. S.;
2007
Organometallics
Chiral mono- and bis-annelated cyclopentadienyl ligands derived from tartaric acid: Synthesis of [(eta(5)-cyclopentadienyl)RuCl(cod)] and [(eta(5)-cyclopentadienyl)(eta(6)-benzene)Ru]PF6 derivatives
Validated
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26
15
3722
3728
The synthesis of chiral mono- and bis-annelated 1,3-cyclopentadienes derived from tartaric acid, a chiral pool starting material, is described. In addition to known functionalized chiral 1,3-cyclopentadienes, new derivatives have also been structurally characterized by X-ray crystallographic and NMR spectroscopic studies. Neutral and cationic ruthenium(II) complexes, containing a mono-annelated chiral cyclopentadienyl ligand (1), have been successfully prepared. The X-ray crystal structure of [(eta(5)-Cp')Ru(eta(6)-benzene)][PF6], Cp'=1, has been determined.
10.1021/om700393b
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