Peer-Reviewed Journal Details
Mandatory Fields
Shinde N.M.;Shinde P.V.;Yun J.M.;Gunturu K.C.;Mane R.S.;O'dwyer C.;Kim K.H.
2020
January
ACS Omega
NiF2 Nanorod Arrays for Supercapattery Applications
Validated
Optional Fields
5
17
9768
9774
A electrode for energy storage cells is possible directly on Ni foam, using a simple reduction process to form NiF2 nanorod arrays (NA). We demonstrate NiF2@Ni NA for a symmetric electrochemical supercapattery electrode. With an areal specific capacitance of 51 F cm-2 at 0.25 mA cm-2 current density and 94% cycling stability, a NiF2@Ni electrode can exhibit supercapattery behavior, a combination of supercapacitor and battery-like redox. The symmetric electrochemical supercapattery delivers 31 W h m-2 energy density and 797 W m-2 power density with 83% retention in a 1 M KOH electrolyte, constituting a step toward manufacturing a laboratory-scale energy storage device based on metal halides. Producing self-grown hierarchically porous nanostructured electrodes on three-dimensional metal foams by displacement reactions may be useful for other metal halides as electrodes for supercapacitors, supercapatteries, and lithium-ion batteries.
2470-1343
https://pubs.acs.org/doi/abs/10.1021/acsomega.9b04219
10.1021/acsomega.9b04219
Grant Details