Peer-Reviewed Journal Details
Mandatory Fields
Browne, Wesley R. and Passaniti, Paolo and Gandolfi, Maria Teresa and Ballardini, Roberto and Henry, William and Guckian, Adrian and O'Boyle, Noel and McGarvey, John J. and Vos, Johannes G.;
2007
Inorganica Chimica Acta
Probing inter-ligand excited state interaction in homo and heteroleptic ruthenium(II) polypyridyl complexes using selective deuteriation
Validated
()
Optional Fields
360
3
1183
1190
The effect of deuteriation on the photophysical properties of two series of regioselectively deuteriated Ru(II) complexes ([Ru(bipy)(x)(ph(2)phen)(3-x)](2+), where x=0-3 and ph(2)phen is 4,7-diphenyt-1,10-phenanthroline and [Ru(biPY)(2)(dcbipy(2-))], where H(2)dcbipy is 4,4'-dicarboxy-2,2'-bipyridyl) is reported. Although overall, deuteriation results in an increase in emission lifetime for all complexes, the effect of substitution of hydrogen for deuterium shows strong regioselectivity both in terms of the ligand and the position on individual ligands that are exchanged. (c) 2006 Elsevier B.V. All rights reserved.
10.1016/j.ica.2006.08.049
Grant Details